Intercalation and Stitching of Graphite Oxide with Diaminoalkanes

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Intercalation and stitching of graphite oxide with diaminoalkanes.

The intercalation reaction of graphite oxide with diaminoalkanes, with the general formula H2N(CH2)nNH2 (n = 4-10), was studied as a method for synthesizing pillared graphite with tailored interlayer spacing. Interlayer spacings from 0.8 to 1.0 nm were tailored by varying the size of the intercalant from (CH2)4 to (CH2)10. X-ray diffraction and infrared spectroscopy were used to confirm interca...

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ژورنال

عنوان ژورنال: Langmuir

سال: 2007

ISSN: 0743-7463,1520-5827

DOI: 10.1021/la0633839